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Atomic Defect Lines Suppress Deactivation of Iron Oxide Catalysts

Research led by Dario Stacchiola, leader of the Interface Science and Catalysis Group at Brookhaven National Laboratory and an adjunct professor in the Chemistry Department in the College of Arts and Sciences at Stony Brook University, could enable inexpensive, widely available metals like iron to be efficient and stable catalysts.

Catalysts, or substances that accelerate chemical reactions, have various industrial applications. One widely used catalyst in catalytic converters is palladium, which helps turn toxic carbon monoxide and hydrocarbons from vehicle exhaust into carbon dioxide and water through oxidation. But like other precious metals such as platinum, palladium is rare. Because of its limited supply, palladium is an expensive commodity.

BNL research
Stony Brook’s Dario Stacchiola and BNL staff scientist Ashley Head with a state-of-the-art instrument for ambient-pressure scanning tunneling microscopy and x-ray photoelectron spectroscopy—two kinds of surface-science techniques.

Replacing precious metal catalysts with those based on more abundant metals such as iron would significantly decrease their cost. However, iron catalysts, while highly efficient, tend to quickly deactivate. For example, iron oxide catalysts become “poisoned” when their surfaces are covered by carbon species formed during reactions with carbon-containing molecules, such as when carbon monoxide dissociates into carbon and oxygen. Carbon deposited on the catalyst surface blocks the active sites and prevents further reactions from taking place, thus “poisoning” and ultimately deactivating the catalyst.

“One form of iron oxide, FeO, is a very inexpensive material that is active for oxidation, but too active for its own good,” Stacchiola said. “Creating structures with iron that are active enough to promote the reaction without becoming deactivated could open the door to using these catalysts in practical applications.”

Stacchiola and collaborators found a structure that might be able to do just that. The scientists prepared a thin layer of FeO nanoparticles on top of a gold surface and discovered that dislocation lines appearing on the FeO surface are very active yet do not get poisoned. These defect lines consist of iron atoms surrounded by four oxygen atoms instead of the normal three.

The team detected the defects in high-resolution images recorded via low-temperature scanning tunneling microscopy (STM) at the CFN Proximal Probes Facility and Nanjing University of Science and Technology in China, where team member and former CFN postdoc Tianchao Niu is now a professor. In STM, electrical current is measured as electrons tunnel between a sample surface and a metal tip that scans across the surface.

The scientists then studied the oxidation and reduction of FeO in environments of oxygen gas and carbon monoxide, respectively. To monitor the atomic and chemical structure of the catalyst, they performed surface-science studies at room temperature and ambient pressure (AP). In particular, they used a state-of-the-art AP-STM instrument available to academic and industrial users at the CFN.

“We wanted to see if the catalyst would be active at moderate conditions because high temperatures or pressures can dissociate carbon monoxide into carbon, deactivating the catalyst,” said Stacchiola. “By conducting these studies at ambient pressure, we can observe how the material changes while it is working. Only then can we understand the chemical processes happening at the atomic and molecular level.”

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